Synthesis, characterization and sustained release properties of zinc-aluminium-9-hydroxy-9-flourenecarboxylate nanocomposite

S. H. Sarijo, A. Ahmad, Zaemah Jubri @ Mohd Zufri

Research output: Chapter in Book/Report/Conference proceedingConference contribution

1 Citation (Scopus)

Abstract

Zn-Al-9-hydroxy-9-flourenecarboxylate-layered double hydroxide, ZAF nanocomposite was successfully synthesized by direct self-assembly method with Zn to Al molar ratio, R = 4 and 0.4 M 9-hydroxy-9-flourenecarboxylate, 9H9F. Due to the inclusion of a new anion, 9H9F basal spacing expanded from 8.9 Å in the Zn-Al-layered double hydroxide, ZAL to 13.2 Å in the ZAF. The FTIR spectra of the hybrid nanocomposite show resemblance peaks of the ZAL and 9H9F indicating the inclusion of the organic compound into the LDH interlamellae. The percentage loading of 9H9F was found to be 75.9 % (w/w). Sustained release of 9H9F from ZAF into various aqueous solutions was found to be dependent on the incoming anion, with the percentage saturated release of 94%, 72%, and 15% in sodium phosphate, sodium sulfate and sodium chloride aqueous solution 0.0005 M, respectively. This study indicates that ZAL can be used as a host carrier for plant growth regulator, 9H9F with sustained release capability.

Original languageEnglish
Title of host publicationEquipment Manufacturing Technology
Pages102-106
Number of pages5
DOIs
Publication statusPublished - 01 Jan 2012
Event2nd International Conference on Advances in Materials and Manufacturing Processes, ICAMMP 2011 - Guilin, China
Duration: 16 Dec 201118 Dec 2011

Publication series

NameAdvanced Materials Research
Volume422
ISSN (Print)1022-6680

Other

Other2nd International Conference on Advances in Materials and Manufacturing Processes, ICAMMP 2011
CountryChina
CityGuilin
Period16/12/1118/12/11

Fingerprint

Nanocomposites
Zinc
Negative ions
Aluminum
Sodium sulfate
Sodium chloride
Organic compounds
Self assembly
Phosphates
Sodium

All Science Journal Classification (ASJC) codes

  • Engineering(all)

Cite this

Sarijo, S. H. ; Ahmad, A. ; Jubri @ Mohd Zufri, Zaemah. / Synthesis, characterization and sustained release properties of zinc-aluminium-9-hydroxy-9-flourenecarboxylate nanocomposite. Equipment Manufacturing Technology. 2012. pp. 102-106 (Advanced Materials Research).
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title = "Synthesis, characterization and sustained release properties of zinc-aluminium-9-hydroxy-9-flourenecarboxylate nanocomposite",
abstract = "Zn-Al-9-hydroxy-9-flourenecarboxylate-layered double hydroxide, ZAF nanocomposite was successfully synthesized by direct self-assembly method with Zn to Al molar ratio, R = 4 and 0.4 M 9-hydroxy-9-flourenecarboxylate, 9H9F. Due to the inclusion of a new anion, 9H9F basal spacing expanded from 8.9 {\AA} in the Zn-Al-layered double hydroxide, ZAL to 13.2 {\AA} in the ZAF. The FTIR spectra of the hybrid nanocomposite show resemblance peaks of the ZAL and 9H9F indicating the inclusion of the organic compound into the LDH interlamellae. The percentage loading of 9H9F was found to be 75.9 {\%} (w/w). Sustained release of 9H9F from ZAF into various aqueous solutions was found to be dependent on the incoming anion, with the percentage saturated release of 94{\%}, 72{\%}, and 15{\%} in sodium phosphate, sodium sulfate and sodium chloride aqueous solution 0.0005 M, respectively. This study indicates that ZAL can be used as a host carrier for plant growth regulator, 9H9F with sustained release capability.",
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Sarijo, SH, Ahmad, A & Jubri @ Mohd Zufri, Z 2012, Synthesis, characterization and sustained release properties of zinc-aluminium-9-hydroxy-9-flourenecarboxylate nanocomposite. in Equipment Manufacturing Technology. Advanced Materials Research, vol. 422, pp. 102-106, 2nd International Conference on Advances in Materials and Manufacturing Processes, ICAMMP 2011, Guilin, China, 16/12/11. https://doi.org/10.4028/www.scientific.net/AMR.422.102

Synthesis, characterization and sustained release properties of zinc-aluminium-9-hydroxy-9-flourenecarboxylate nanocomposite. / Sarijo, S. H.; Ahmad, A.; Jubri @ Mohd Zufri, Zaemah.

Equipment Manufacturing Technology. 2012. p. 102-106 (Advanced Materials Research; Vol. 422).

Research output: Chapter in Book/Report/Conference proceedingConference contribution

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