Synthesis and structural consideration of Metal-Organic Framework (MOF) coordination polymer with various metal linker ratios

Halina Misran, Atiah Mohd Aminuddin, Faizul Akmal Mohd Zini, Ramesh Singh

Research output: Chapter in Book/Report/Conference proceedingConference contribution

Abstract

Metal-organic framework MOF-5 (i.e. IRMOF-1) with the chemical structure of Zn4O(BDC)3 were successfully synthesized using room temperature synthesis approach of direct-mixing method ans liquid-crystal templating method. The metal clusters organic linker used was benzenedicarboxylic acid (BDC). Direct-mixing approach resulted in MOF-5 with tetragonal cell while the liquid-crystal templating method resulted in cubic structure. The metal/linker ratios were varied from 0.1 to 1 to study the effect of metal linker on the formation of MOF-5 materials and their characteristics. The crystallinity of the evacuated framework MOF-5 materials were increased when the metal/organic linker ratios were increased from 0.3 to 0.5. However, the cubic structure of the evacuated framework was relatively disrupted at metal/linker ratio 0.7.

Original languageEnglish
Title of host publicationFracture and Strength of Solids VII
Pages1103-1108
Number of pages6
DOIs
Publication statusPublished - 04 Feb 2011
Event8th International Conference on Fracture and Strength of Solids 2010, FEOFS2010 - Kuala Lumpur, Malaysia
Duration: 07 Jun 201009 Jun 2010

Publication series

NameKey Engineering Materials
Volume462-463
ISSN (Print)1013-9826

Other

Other8th International Conference on Fracture and Strength of Solids 2010, FEOFS2010
CountryMalaysia
CityKuala Lumpur
Period07/06/1009/06/10

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All Science Journal Classification (ASJC) codes

  • Materials Science(all)
  • Mechanics of Materials
  • Mechanical Engineering

Cite this

Misran, H., Aminuddin, A. M., Zini, F. A. M., & Singh, R. (2011). Synthesis and structural consideration of Metal-Organic Framework (MOF) coordination polymer with various metal linker ratios. In Fracture and Strength of Solids VII (pp. 1103-1108). (Key Engineering Materials; Vol. 462-463). https://doi.org/10.4028/www.scientific.net/KEM.462-463.1103