Synthesis and structural consideration of Metal-Organic Framework (MOF) coordination polymer with various metal linker ratios

Halina Misran, Atiah Mohd Aminuddin, F. A M Zini, Ramesh Singh

Research output: Chapter in Book/Report/Conference proceedingConference contribution

Abstract

Metal-organic framework MOF-5 (i.e. IRMOF-1) with the chemical structure of Zn4O(BDC)3 were successfully synthesized using room temperature synthesis approach of direct-mixing method ans liquid-crystal templating method. The metal clusters organic linker used was benzenedicarboxylic acid (BDC). Direct-mixing approach resulted in MOF-5 with tetragonal cell while the liquid-crystal templating method resulted in cubic structure. The metal/linker ratios were varied from 0.1 to 1 to study the effect of metal linker on the formation of MOF-5 materials and their characteristics. The crystallinity of the evacuated framework MOF-5 materials were increased when the metal/organic linker ratios were increased from 0.3 to 0.5. However, the cubic structure of the evacuated framework was relatively disrupted at metal/linker ratio 0.7.

Original languageEnglish
Title of host publicationFracture and Strength of Solids VII
Pages1103-1108
Number of pages6
DOIs
Publication statusPublished - 04 Feb 2011
Event8th International Conference on Fracture and Strength of Solids 2010, FEOFS2010 - Kuala Lumpur, Malaysia
Duration: 07 Jun 201009 Jun 2010

Publication series

NameKey Engineering Materials
Volume462-463
ISSN (Print)1013-9826

Other

Other8th International Conference on Fracture and Strength of Solids 2010, FEOFS2010
CountryMalaysia
CityKuala Lumpur
Period07/06/1009/06/10

Fingerprint

Polymers
Metals
Liquid Crystals
Liquid crystals
Acids

All Science Journal Classification (ASJC) codes

  • Mechanical Engineering
  • Mechanics of Materials
  • Materials Science(all)

Cite this

Misran, H., Aminuddin, A. M., Zini, F. A. M., & Singh, R. (2011). Synthesis and structural consideration of Metal-Organic Framework (MOF) coordination polymer with various metal linker ratios. In Fracture and Strength of Solids VII (pp. 1103-1108). (Key Engineering Materials; Vol. 462-463). https://doi.org/10.4028/www.scientific.net/KEM.462-463.1103
Misran, Halina ; Aminuddin, Atiah Mohd ; Zini, F. A M ; Singh, Ramesh. / Synthesis and structural consideration of Metal-Organic Framework (MOF) coordination polymer with various metal linker ratios. Fracture and Strength of Solids VII. 2011. pp. 1103-1108 (Key Engineering Materials).
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Misran, H, Aminuddin, AM, Zini, FAM & Singh, R 2011, Synthesis and structural consideration of Metal-Organic Framework (MOF) coordination polymer with various metal linker ratios. in Fracture and Strength of Solids VII. Key Engineering Materials, vol. 462-463, pp. 1103-1108, 8th International Conference on Fracture and Strength of Solids 2010, FEOFS2010, Kuala Lumpur, Malaysia, 07/06/10. https://doi.org/10.4028/www.scientific.net/KEM.462-463.1103

Synthesis and structural consideration of Metal-Organic Framework (MOF) coordination polymer with various metal linker ratios. / Misran, Halina; Aminuddin, Atiah Mohd; Zini, F. A M; Singh, Ramesh.

Fracture and Strength of Solids VII. 2011. p. 1103-1108 (Key Engineering Materials; Vol. 462-463).

Research output: Chapter in Book/Report/Conference proceedingConference contribution

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