Synthesis and characterizations of MOF-199 using PODFA as porogen for CO2 adsorption applications

Research output: Chapter in Book/Report/Conference proceedingConference contribution

Abstract

Copper-based metal-organic framework (MOF-199, also known as Cu-BTC and HKUST-1) materials were successfully synthesized by hydrothermal method using renewable straight-chain fatty alcohol with eight carbon chain length (i.e. octyl alcohol). The addition of palm oil derived fatty alcohol (PODFA) was suggested to act as porogen (structure directing agent) that aided the particle formation and flexible porous structure. This synthesis approach was environmental-friendly and sustainable by utilizing the fatty alcohols originated from biomass such as palm oil. The resulting MOF-199 materials exhibited single crystalline octahedral morphology structure by X-ray diffraction analyses and SEM images. The optimum ratio of octyl alcohol exhibited well-defined single octahedral particles at size range of ca. 10-50 μm and reduced byproduct formation of cuprous oxide at high temperature synthesis. The nature of MOF-199 having apparently high surface area, high pore volume and low density provided the possibility in carbon capture storage. The CO2 adsorption capacity of MOF-199 investigated using high pressure volumetric analyser (HPVA-II) at ambient temperature (i.e. 25 °C) was found to be at maximum working capacity.

Original languageEnglish
Title of host publicationCurrent Trends in Materials Engineering
EditorsMohd Edeerozey Abd Manaf, T. Joseph Sahaya Anand, Md Nizam Abd Rahman, Mohd Sanusi Abdul Aziz, Radzali Othman
PublisherTrans Tech Publications Ltd
Pages44-49
Number of pages6
ISBN (Print)9783035710199
DOIs
Publication statusPublished - 01 Jan 2016
Event24th Scientific Conference of the Microscopy Society Malaysia, SCMSM 2015 - Malacca, Malaysia
Duration: 02 Dec 201504 Dec 2015

Publication series

NameKey Engineering Materials
Volume694
ISSN (Print)1013-9826
ISSN (Electronic)1662-9795

Other

Other24th Scientific Conference of the Microscopy Society Malaysia, SCMSM 2015
CountryMalaysia
CityMalacca
Period02/12/1504/12/15

All Science Journal Classification (ASJC) codes

  • Materials Science(all)
  • Mechanics of Materials
  • Mechanical Engineering

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    Mahadi, N., Misran, H., & Othman, S. Z. (2016). Synthesis and characterizations of MOF-199 using PODFA as porogen for CO2 adsorption applications. In M. E. A. Manaf, T. J. S. Anand, M. N. A. Rahman, M. S. A. Aziz, & R. Othman (Eds.), Current Trends in Materials Engineering (pp. 44-49). (Key Engineering Materials; Vol. 694). Trans Tech Publications Ltd. https://doi.org/10.4028/www.scientific.net/KEM.694.44