Renewable decyl-alcohol templated synthesis of Si-Cu core-shell nanocomposite

M. A. Salim, Halina Misran, Siti Zubaidah Othman, N. N.H. Shah, N. A.A. Razak, Abreeza Noorlina Abd. Manap

Research output: Contribution to journalConference article

1 Citation (Scopus)

Abstract

Monodispersed silica spheres with particles size of ca. 450 nm were successfully synthesized using a modified Stöber method. The synthesized monodispersed silica spheres were successfully coated with copper using modified sol-gel method employing nonsurfactant surface modifiers and catalyst. A renewable palm oil based decyl-alcohol (C10) as nonsurfactant surface modifiers and catalyst were used to modify the silica surfaces prior to coating with copper. The X-ray diffraction patterns of Si-Cu core-shell exhibited a broad peak corresponding to amorphous silica networks and monoclinic CuO phase. It was found that samples modified in the presence of 1 ml catalyst exhibited homogeneous deposition. The surface area of core materials (SiO2) was at ca. 7.04 m2/g and Si-Cu core-shell was at ca. 8.21 m2/g. The band gap of samples prepared with and without catalyst was calculated to be ca. 2.45 eV and ca. 3.90 eV respectively based on the UV-vis absorption spectrum of the product.

Original languageEnglish
Article number012054
JournalIOP Conference Series: Earth and Environmental Science
Volume16
Issue number1
DOIs
Publication statusPublished - 01 Jan 2013
Event26th IAHR Symposium on Hydraulic Machinery and Systems - Beijing, China
Duration: 19 Aug 201223 Aug 2012

    Fingerprint

All Science Journal Classification (ASJC) codes

  • Environmental Science(all)
  • Earth and Planetary Sciences(all)

Cite this