Recent advances in renewable hydrogen production by thermo-catalytic conversion of biomass-derived glycerol

Overview of prospects and challenges

Bamidele Victor Ayodele, Tuan Ab Rashid Tuan Abdullah, May Ali Alsaffar, Siti Indati Mustapa @ Jaafar, Siti Fatihah Salleh

Research output: Contribution to journalArticle

Abstract

Glycerol is the main by-products obtained from the transesterification of vegetable oils and animal fats to produce biodiesel which is an important biofuel used for transportation. The increase in the global energy demand has pushed up the production of biodiesel with a corresponding increase in glycerol production over the years. The thermo-catalytic process is gaining wide popularity as sustainable technical routes of converting glycerol to renewable hydrogen. There exists a great potential of utilizing hydrogen as a critical part of a more sustainable and secure energy mix. Hence, this study focusses on the review of the recent advances and development in the thermo-catalytic conversion of glycerol to renewable hydrogen in the last one decade. The analysis of the reviewed articles showed that substantial efforts had been made in the application of thermo-catalytic process for the conversion of glycerol to renewable hydrogen. Glycerol reforming using steam, carbon dioxide (CO2) and oxygen (O2) have received significant research attention and have been found to have great potential as technological routes for hydrogen production. Whereas, the use of the photocatalytic glycerol reforming has the advantages of energy-saving by utilizing the vast available solar resources and suitable photocatalysts. However, each of the thermo-catalytic processes exhibits inherent challenges which have been a bottleneck to the development of the process to industrial scales. Nevertheless, the prospect of employing each of the thermo-catalytic processes for hydrogen production via glycerol conversion was identified with the possible suggestion of strategies of overcoming the challenges.

Original languageEnglish
JournalInternational Journal of Hydrogen Energy
DOIs
Publication statusAccepted/In press - 01 Jan 2019

Fingerprint

hydrogen production
biomass
Hydrogen production
glycerols
Glycerol
Biomass
Hydrogen
hydrogen
Biodiesel
routes
vegetables
Vegetable oils
Steam reforming
Transesterification
fats
Biofuels
Reforming reactions
Photocatalysts
Oils and fats
steam

All Science Journal Classification (ASJC) codes

  • Renewable Energy, Sustainability and the Environment
  • Fuel Technology
  • Condensed Matter Physics
  • Energy Engineering and Power Technology

Cite this

@article{adc96bbcee0848b8a309008aa67846e8,
title = "Recent advances in renewable hydrogen production by thermo-catalytic conversion of biomass-derived glycerol: Overview of prospects and challenges",
abstract = "Glycerol is the main by-products obtained from the transesterification of vegetable oils and animal fats to produce biodiesel which is an important biofuel used for transportation. The increase in the global energy demand has pushed up the production of biodiesel with a corresponding increase in glycerol production over the years. The thermo-catalytic process is gaining wide popularity as sustainable technical routes of converting glycerol to renewable hydrogen. There exists a great potential of utilizing hydrogen as a critical part of a more sustainable and secure energy mix. Hence, this study focusses on the review of the recent advances and development in the thermo-catalytic conversion of glycerol to renewable hydrogen in the last one decade. The analysis of the reviewed articles showed that substantial efforts had been made in the application of thermo-catalytic process for the conversion of glycerol to renewable hydrogen. Glycerol reforming using steam, carbon dioxide (CO2) and oxygen (O2) have received significant research attention and have been found to have great potential as technological routes for hydrogen production. Whereas, the use of the photocatalytic glycerol reforming has the advantages of energy-saving by utilizing the vast available solar resources and suitable photocatalysts. However, each of the thermo-catalytic processes exhibits inherent challenges which have been a bottleneck to the development of the process to industrial scales. Nevertheless, the prospect of employing each of the thermo-catalytic processes for hydrogen production via glycerol conversion was identified with the possible suggestion of strategies of overcoming the challenges.",
author = "Ayodele, {Bamidele Victor} and {Tuan Abdullah}, {Tuan Ab Rashid} and Alsaffar, {May Ali} and {Mustapa @ Jaafar}, {Siti Indati} and Salleh, {Siti Fatihah}",
year = "2019",
month = "1",
day = "1",
doi = "10.1016/j.ijhydene.2019.08.002",
language = "English",
journal = "International Journal of Hydrogen Energy",
issn = "0360-3199",
publisher = "Elsevier Limited",

}

TY - JOUR

T1 - Recent advances in renewable hydrogen production by thermo-catalytic conversion of biomass-derived glycerol

T2 - Overview of prospects and challenges

AU - Ayodele, Bamidele Victor

AU - Tuan Abdullah, Tuan Ab Rashid

AU - Alsaffar, May Ali

AU - Mustapa @ Jaafar, Siti Indati

AU - Salleh, Siti Fatihah

PY - 2019/1/1

Y1 - 2019/1/1

N2 - Glycerol is the main by-products obtained from the transesterification of vegetable oils and animal fats to produce biodiesel which is an important biofuel used for transportation. The increase in the global energy demand has pushed up the production of biodiesel with a corresponding increase in glycerol production over the years. The thermo-catalytic process is gaining wide popularity as sustainable technical routes of converting glycerol to renewable hydrogen. There exists a great potential of utilizing hydrogen as a critical part of a more sustainable and secure energy mix. Hence, this study focusses on the review of the recent advances and development in the thermo-catalytic conversion of glycerol to renewable hydrogen in the last one decade. The analysis of the reviewed articles showed that substantial efforts had been made in the application of thermo-catalytic process for the conversion of glycerol to renewable hydrogen. Glycerol reforming using steam, carbon dioxide (CO2) and oxygen (O2) have received significant research attention and have been found to have great potential as technological routes for hydrogen production. Whereas, the use of the photocatalytic glycerol reforming has the advantages of energy-saving by utilizing the vast available solar resources and suitable photocatalysts. However, each of the thermo-catalytic processes exhibits inherent challenges which have been a bottleneck to the development of the process to industrial scales. Nevertheless, the prospect of employing each of the thermo-catalytic processes for hydrogen production via glycerol conversion was identified with the possible suggestion of strategies of overcoming the challenges.

AB - Glycerol is the main by-products obtained from the transesterification of vegetable oils and animal fats to produce biodiesel which is an important biofuel used for transportation. The increase in the global energy demand has pushed up the production of biodiesel with a corresponding increase in glycerol production over the years. The thermo-catalytic process is gaining wide popularity as sustainable technical routes of converting glycerol to renewable hydrogen. There exists a great potential of utilizing hydrogen as a critical part of a more sustainable and secure energy mix. Hence, this study focusses on the review of the recent advances and development in the thermo-catalytic conversion of glycerol to renewable hydrogen in the last one decade. The analysis of the reviewed articles showed that substantial efforts had been made in the application of thermo-catalytic process for the conversion of glycerol to renewable hydrogen. Glycerol reforming using steam, carbon dioxide (CO2) and oxygen (O2) have received significant research attention and have been found to have great potential as technological routes for hydrogen production. Whereas, the use of the photocatalytic glycerol reforming has the advantages of energy-saving by utilizing the vast available solar resources and suitable photocatalysts. However, each of the thermo-catalytic processes exhibits inherent challenges which have been a bottleneck to the development of the process to industrial scales. Nevertheless, the prospect of employing each of the thermo-catalytic processes for hydrogen production via glycerol conversion was identified with the possible suggestion of strategies of overcoming the challenges.

UR - http://www.scopus.com/inward/record.url?scp=85071105154&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=85071105154&partnerID=8YFLogxK

U2 - 10.1016/j.ijhydene.2019.08.002

DO - 10.1016/j.ijhydene.2019.08.002

M3 - Article

JO - International Journal of Hydrogen Energy

JF - International Journal of Hydrogen Energy

SN - 0360-3199

ER -