Preparation and thermal properties of form-stable phase change materials composed of palmitic acid/polypyrrole/graphene nanoplatelets

Mahyar Silakhori, Hadi Fauzi, Mohammad R. Mahmoudian, Hendrik Simon Cornelis Metselaar, T.m. Indra Mahlia, Hossein Mohammad Khanlou

Research output: Contribution to journalArticle

29 Citations (Scopus)

Abstract

In this study, the thermal conductivity of form-stable phase change materials (PCMs) is improved by the addition of graphene nanoplatelets (GNPs). In the first step, the dispersed GNPs were mixed with palmitic acid (PA) particles using an ultra-sonication method. Then, the prepared material was added to form-stable phase change materials (PA/PPy) obtained by a polymerisation technique. The amount of PA particles remained constant in the prepared form-stable phase change materials. FT-IR and SEM analyses were used to investigate the structure and surface morphology of form-stable PCMs, respectively. The thermal properties, stability and conductivity of the materials were also characterised using DSC, TGA and thermal conductivity analysis, respectively. The results indicated that GNPs had a significant effect on improving the thermal conductivity of form-stable PCMs (PA/PPy). By doping 1.6% of GNPs, the thermal conductivity and thermal capacity of PA/PPy/GNPs form-stable PCMs could reach up to 0.43 W/m K and 151 J/g, respectively. In other words, thermal conductivity increased by 34.3% in comparison with PA/PPy form-stable PCMs. The prepared PA/PPy/GNPs form-stable PCMs are anticipated to show improved performance for solar thermal energy storage applications.

Original languageEnglish
Pages (from-to)189-195
Number of pages7
JournalEnergy and Buildings
Volume99
DOIs
Publication statusPublished - 10 May 2015

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Palmitic acid
Phase change materials
Polypyrroles
Graphene
Thermodynamic properties
Thermal conductivity
Sonication
Thermal energy
Energy storage
Specific heat
Surface morphology
Polymerization
Doping (additives)
Scanning electron microscopy

All Science Journal Classification (ASJC) codes

  • Civil and Structural Engineering
  • Building and Construction
  • Mechanical Engineering
  • Electrical and Electronic Engineering

Cite this

Silakhori, Mahyar ; Fauzi, Hadi ; Mahmoudian, Mohammad R. ; Metselaar, Hendrik Simon Cornelis ; Mahlia, T.m. Indra ; Khanlou, Hossein Mohammad. / Preparation and thermal properties of form-stable phase change materials composed of palmitic acid/polypyrrole/graphene nanoplatelets. In: Energy and Buildings. 2015 ; Vol. 99. pp. 189-195.
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Preparation and thermal properties of form-stable phase change materials composed of palmitic acid/polypyrrole/graphene nanoplatelets. / Silakhori, Mahyar; Fauzi, Hadi; Mahmoudian, Mohammad R.; Metselaar, Hendrik Simon Cornelis; Mahlia, T.m. Indra; Khanlou, Hossein Mohammad.

In: Energy and Buildings, Vol. 99, 10.05.2015, p. 189-195.

Research output: Contribution to journalArticle

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AU - Silakhori, Mahyar

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AU - Metselaar, Hendrik Simon Cornelis

AU - Mahlia, T.m. Indra

AU - Khanlou, Hossein Mohammad

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