Facile synthesis and thermal performances of stearic acid/titania core/shell nanocapsules by sol-gel method

Sara Tahan Latibari, Mohammad Mehrali, Mehdi Mehrali, Amalina Binti Muhammad Afifi, T.m. Indra Mahlia, Amir Reza Akhiani, Hendrik Simon Cornelis Metselaar

Research output: Contribution to journalArticle

36 Citations (Scopus)

Abstract

In order to improve the thermal properties of PCMs (phase change materials), in this study, a new series of NEPCMs (nanoencapsulated phase change materials) were synthesized using a sol-gel method with SA (stearic acid) as the core and TiO 2 (titania) as the shell material. The effects of the weight ratios of the SA/titania precursor TTIP (titanium tetraisopropoxide) on the morphology, thermal performance and thermal conductivity of the prepared nanocapsules are discussed. The experimental results indicate that the SA was encapsulated in spheres with minimum and maximum diameters of 583.4 and 946.4 nm, at encapsulation ratios between 30.36% and 64.76%. The results indicated that there was no chemical interaction between the core and shell materials, SA and TiO 2 , which were compatible with each other under controlled synthesis conditions of pH 10. The NEPCMs with high mass ratios of SA/TTIP exhibited enhanced phase change properties and higher encapsulation efficiencies but lower thermal conductivities than NEPCMs with low mass ratios. Good thermal reliability and chemical stability of the NEPCMs were obtained by cycling the material through 2500 melting/solidifying cycles. In conclusion, the outstanding thermal stability and reliability of the prepared nanocapsules make these materials appropriate phase change materials for thermal energy storage applications.

Original languageEnglish
Pages (from-to)635-644
Number of pages10
JournalEnergy
Volume85
DOIs
Publication statusPublished - 01 Jun 2015

Fingerprint

Nanocapsules
Stearic acid
Phase change materials
Sol-gel process
Titanium
Encapsulation
Thermal conductivity
Chemical stability
Thermal energy
Energy storage
Hot Temperature
Melting
Thermodynamic stability
Thermodynamic properties

All Science Journal Classification (ASJC) codes

  • Civil and Structural Engineering
  • Building and Construction
  • Pollution
  • Mechanical Engineering
  • Industrial and Manufacturing Engineering
  • Electrical and Electronic Engineering

Cite this

Tahan Latibari, S., Mehrali, M., Mehrali, M., Afifi, A. B. M., Mahlia, T. M. I., Akhiani, A. R., & Metselaar, H. S. C. (2015). Facile synthesis and thermal performances of stearic acid/titania core/shell nanocapsules by sol-gel method. Energy, 85, 635-644. https://doi.org/10.1016/j.energy.2015.04.008
Tahan Latibari, Sara ; Mehrali, Mohammad ; Mehrali, Mehdi ; Afifi, Amalina Binti Muhammad ; Mahlia, T.m. Indra ; Akhiani, Amir Reza ; Metselaar, Hendrik Simon Cornelis. / Facile synthesis and thermal performances of stearic acid/titania core/shell nanocapsules by sol-gel method. In: Energy. 2015 ; Vol. 85. pp. 635-644.
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Tahan Latibari, S, Mehrali, M, Mehrali, M, Afifi, ABM, Mahlia, TMI, Akhiani, AR & Metselaar, HSC 2015, 'Facile synthesis and thermal performances of stearic acid/titania core/shell nanocapsules by sol-gel method', Energy, vol. 85, pp. 635-644. https://doi.org/10.1016/j.energy.2015.04.008

Facile synthesis and thermal performances of stearic acid/titania core/shell nanocapsules by sol-gel method. / Tahan Latibari, Sara; Mehrali, Mohammad; Mehrali, Mehdi; Afifi, Amalina Binti Muhammad; Mahlia, T.m. Indra; Akhiani, Amir Reza; Metselaar, Hendrik Simon Cornelis.

In: Energy, Vol. 85, 01.06.2015, p. 635-644.

Research output: Contribution to journalArticle

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T1 - Facile synthesis and thermal performances of stearic acid/titania core/shell nanocapsules by sol-gel method

AU - Tahan Latibari, Sara

AU - Mehrali, Mohammad

AU - Mehrali, Mehdi

AU - Afifi, Amalina Binti Muhammad

AU - Mahlia, T.m. Indra

AU - Akhiani, Amir Reza

AU - Metselaar, Hendrik Simon Cornelis

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Y1 - 2015/6/1

N2 - In order to improve the thermal properties of PCMs (phase change materials), in this study, a new series of NEPCMs (nanoencapsulated phase change materials) were synthesized using a sol-gel method with SA (stearic acid) as the core and TiO 2 (titania) as the shell material. The effects of the weight ratios of the SA/titania precursor TTIP (titanium tetraisopropoxide) on the morphology, thermal performance and thermal conductivity of the prepared nanocapsules are discussed. The experimental results indicate that the SA was encapsulated in spheres with minimum and maximum diameters of 583.4 and 946.4 nm, at encapsulation ratios between 30.36% and 64.76%. The results indicated that there was no chemical interaction between the core and shell materials, SA and TiO 2 , which were compatible with each other under controlled synthesis conditions of pH 10. The NEPCMs with high mass ratios of SA/TTIP exhibited enhanced phase change properties and higher encapsulation efficiencies but lower thermal conductivities than NEPCMs with low mass ratios. Good thermal reliability and chemical stability of the NEPCMs were obtained by cycling the material through 2500 melting/solidifying cycles. In conclusion, the outstanding thermal stability and reliability of the prepared nanocapsules make these materials appropriate phase change materials for thermal energy storage applications.

AB - In order to improve the thermal properties of PCMs (phase change materials), in this study, a new series of NEPCMs (nanoencapsulated phase change materials) were synthesized using a sol-gel method with SA (stearic acid) as the core and TiO 2 (titania) as the shell material. The effects of the weight ratios of the SA/titania precursor TTIP (titanium tetraisopropoxide) on the morphology, thermal performance and thermal conductivity of the prepared nanocapsules are discussed. The experimental results indicate that the SA was encapsulated in spheres with minimum and maximum diameters of 583.4 and 946.4 nm, at encapsulation ratios between 30.36% and 64.76%. The results indicated that there was no chemical interaction between the core and shell materials, SA and TiO 2 , which were compatible with each other under controlled synthesis conditions of pH 10. The NEPCMs with high mass ratios of SA/TTIP exhibited enhanced phase change properties and higher encapsulation efficiencies but lower thermal conductivities than NEPCMs with low mass ratios. Good thermal reliability and chemical stability of the NEPCMs were obtained by cycling the material through 2500 melting/solidifying cycles. In conclusion, the outstanding thermal stability and reliability of the prepared nanocapsules make these materials appropriate phase change materials for thermal energy storage applications.

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