Electroluminescence of ultraviolet and thermally aged low density polyethylene

D. H. Mills, P. L. Lewin, G. Chen, Azrul Mohd Ariffin

Research output: Chapter in Book/Report/Conference proceedingConference contribution

1 Citation (Scopus)

Abstract

It has been postulated that long term ageing of lowdensity polyethylene (LDPE) is due to the movement of space charge within the dielectric. Electroluminescence (EL) has been shown as an alternative method to investigate charge movement within a dielectric. Under ac fields, EL is related to the injection, trapping and recombination of charge carriers at the sample interface. This work investigates the change in EL emission due to the ultraviolet (UV) ageing of additive free 100μm LDPE films. Samples are aged in an oven using a 36W UV fluorescent tube at a temperature of 313K. This causes bond breakages and increased carbonyl and hydroxyl groups as confirmed by Fourier transform infrared (FTIR) spectroscopy. Weibull breakdown statistics also show an increasing reduction in the ac ramp breakdown strength with ageing time. EL images and temporal measurements are collected using a deep cooled charge coupled device (CCD) camera and show an initial reduction in the EL with ageing. Further ageing shows a field dependence of the EL.

Original languageEnglish
Title of host publicationProceedings of the 2010 IEEE International Conference on Solid Dielectrics, ICSD 2010
DOIs
Publication statusPublished - 2010
Event2010 IEEE International Conference on Solid Dielectrics, ICSD 2010 - Potsdam, Germany
Duration: 04 Jul 201009 Jul 2010

Other

Other2010 IEEE International Conference on Solid Dielectrics, ICSD 2010
CountryGermany
CityPotsdam
Period04/07/1009/07/10

Fingerprint

Electroluminescence
Low density polyethylenes
Aging of materials
Polyethylenes
Ovens
CCD cameras
Charge carriers
Electric space charge
Fourier transform infrared spectroscopy
Statistics

All Science Journal Classification (ASJC) codes

  • Electrical and Electronic Engineering

Cite this

Mills, D. H., Lewin, P. L., Chen, G., & Mohd Ariffin, A. (2010). Electroluminescence of ultraviolet and thermally aged low density polyethylene. In Proceedings of the 2010 IEEE International Conference on Solid Dielectrics, ICSD 2010 [5567947] https://doi.org/10.1109/ICSD.2010.5567947
Mills, D. H. ; Lewin, P. L. ; Chen, G. ; Mohd Ariffin, Azrul. / Electroluminescence of ultraviolet and thermally aged low density polyethylene. Proceedings of the 2010 IEEE International Conference on Solid Dielectrics, ICSD 2010. 2010.
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Mills, DH, Lewin, PL, Chen, G & Mohd Ariffin, A 2010, Electroluminescence of ultraviolet and thermally aged low density polyethylene. in Proceedings of the 2010 IEEE International Conference on Solid Dielectrics, ICSD 2010., 5567947, 2010 IEEE International Conference on Solid Dielectrics, ICSD 2010, Potsdam, Germany, 04/07/10. https://doi.org/10.1109/ICSD.2010.5567947

Electroluminescence of ultraviolet and thermally aged low density polyethylene. / Mills, D. H.; Lewin, P. L.; Chen, G.; Mohd Ariffin, Azrul.

Proceedings of the 2010 IEEE International Conference on Solid Dielectrics, ICSD 2010. 2010. 5567947.

Research output: Chapter in Book/Report/Conference proceedingConference contribution

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N2 - It has been postulated that long term ageing of lowdensity polyethylene (LDPE) is due to the movement of space charge within the dielectric. Electroluminescence (EL) has been shown as an alternative method to investigate charge movement within a dielectric. Under ac fields, EL is related to the injection, trapping and recombination of charge carriers at the sample interface. This work investigates the change in EL emission due to the ultraviolet (UV) ageing of additive free 100μm LDPE films. Samples are aged in an oven using a 36W UV fluorescent tube at a temperature of 313K. This causes bond breakages and increased carbonyl and hydroxyl groups as confirmed by Fourier transform infrared (FTIR) spectroscopy. Weibull breakdown statistics also show an increasing reduction in the ac ramp breakdown strength with ageing time. EL images and temporal measurements are collected using a deep cooled charge coupled device (CCD) camera and show an initial reduction in the EL with ageing. Further ageing shows a field dependence of the EL.

AB - It has been postulated that long term ageing of lowdensity polyethylene (LDPE) is due to the movement of space charge within the dielectric. Electroluminescence (EL) has been shown as an alternative method to investigate charge movement within a dielectric. Under ac fields, EL is related to the injection, trapping and recombination of charge carriers at the sample interface. This work investigates the change in EL emission due to the ultraviolet (UV) ageing of additive free 100μm LDPE films. Samples are aged in an oven using a 36W UV fluorescent tube at a temperature of 313K. This causes bond breakages and increased carbonyl and hydroxyl groups as confirmed by Fourier transform infrared (FTIR) spectroscopy. Weibull breakdown statistics also show an increasing reduction in the ac ramp breakdown strength with ageing time. EL images and temporal measurements are collected using a deep cooled charge coupled device (CCD) camera and show an initial reduction in the EL with ageing. Further ageing shows a field dependence of the EL.

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Mills DH, Lewin PL, Chen G, Mohd Ariffin A. Electroluminescence of ultraviolet and thermally aged low density polyethylene. In Proceedings of the 2010 IEEE International Conference on Solid Dielectrics, ICSD 2010. 2010. 5567947 https://doi.org/10.1109/ICSD.2010.5567947