Effect of Synthesis Methods Using Renewable PODFA on Structural Characteristics of Metal-Organic Framework (MOF-5)

S. Z. Othman, H. Misran, W. A. Affendy, N. F. Mahadi

Research output: Contribution to journalConference article

1 Citation (Scopus)

Abstract

In this work, metal-organic framework (MOF-5) syntheses were successfully synthesized with three different methods namely i) modified direct-mixing method ii) microwave assisted method and iii) autoclave assisted method without using surfactants. Palm oil derived fatty alcohol (PODFA), dodecyl alcohol (C8) was used as renewable non-surfactant template. Four prominent peaks were observed in all three samples attributable to the reflection planes of (200), (220), (400) and (420) of a cubic structure at ca. 2θ = 6.9°, 9.6°, 13.7° and 15.2°. The morphology of MOF-5 produced using modified direct-mixing method was faceted structure with average size of ca. 1 μm. In addition, the morphology of MOF-5 produced using microwave assisted synthesis was cubic structure with average size of ca. 8.34 μm. However, the morphology of MOF-5 using autoclave assisted method was interpenetrated cubic with average size of ca. 22.65 μm.

Original languageEnglish
Article number012060
JournalIOP Conference Series: Earth and Environmental Science
Volume32
Issue number1
DOIs
Publication statusPublished - 19 Apr 2016
Event2nd International Conference on Advances in Renewable Energy and Technologies, ICARET 2016 - Putrajaya, Malaysia
Duration: 23 Feb 201625 Feb 2016

Fingerprint

alcohol
oil
metal
surfactant
effect
method
microwave

All Science Journal Classification (ASJC) codes

  • Environmental Science(all)
  • Earth and Planetary Sciences(all)

Cite this

@article{c6c84127d9dc4703bcf23c4f8310224c,
title = "Effect of Synthesis Methods Using Renewable PODFA on Structural Characteristics of Metal-Organic Framework (MOF-5)",
abstract = "In this work, metal-organic framework (MOF-5) syntheses were successfully synthesized with three different methods namely i) modified direct-mixing method ii) microwave assisted method and iii) autoclave assisted method without using surfactants. Palm oil derived fatty alcohol (PODFA), dodecyl alcohol (C8) was used as renewable non-surfactant template. Four prominent peaks were observed in all three samples attributable to the reflection planes of (200), (220), (400) and (420) of a cubic structure at ca. 2θ = 6.9°, 9.6°, 13.7° and 15.2°. The morphology of MOF-5 produced using modified direct-mixing method was faceted structure with average size of ca. 1 μm. In addition, the morphology of MOF-5 produced using microwave assisted synthesis was cubic structure with average size of ca. 8.34 μm. However, the morphology of MOF-5 using autoclave assisted method was interpenetrated cubic with average size of ca. 22.65 μm.",
author = "Othman, {S. Z.} and H. Misran and Affendy, {W. A.} and Mahadi, {N. F.}",
year = "2016",
month = "4",
day = "19",
doi = "10.1088/1755-1315/32/1/012060",
language = "English",
volume = "32",
journal = "IOP Conference Series: Earth and Environmental Science",
issn = "1755-1307",
publisher = "IOP Publishing Ltd.",
number = "1",

}

Effect of Synthesis Methods Using Renewable PODFA on Structural Characteristics of Metal-Organic Framework (MOF-5). / Othman, S. Z.; Misran, H.; Affendy, W. A.; Mahadi, N. F.

In: IOP Conference Series: Earth and Environmental Science, Vol. 32, No. 1, 012060, 19.04.2016.

Research output: Contribution to journalConference article

TY - JOUR

T1 - Effect of Synthesis Methods Using Renewable PODFA on Structural Characteristics of Metal-Organic Framework (MOF-5)

AU - Othman, S. Z.

AU - Misran, H.

AU - Affendy, W. A.

AU - Mahadi, N. F.

PY - 2016/4/19

Y1 - 2016/4/19

N2 - In this work, metal-organic framework (MOF-5) syntheses were successfully synthesized with three different methods namely i) modified direct-mixing method ii) microwave assisted method and iii) autoclave assisted method without using surfactants. Palm oil derived fatty alcohol (PODFA), dodecyl alcohol (C8) was used as renewable non-surfactant template. Four prominent peaks were observed in all three samples attributable to the reflection planes of (200), (220), (400) and (420) of a cubic structure at ca. 2θ = 6.9°, 9.6°, 13.7° and 15.2°. The morphology of MOF-5 produced using modified direct-mixing method was faceted structure with average size of ca. 1 μm. In addition, the morphology of MOF-5 produced using microwave assisted synthesis was cubic structure with average size of ca. 8.34 μm. However, the morphology of MOF-5 using autoclave assisted method was interpenetrated cubic with average size of ca. 22.65 μm.

AB - In this work, metal-organic framework (MOF-5) syntheses were successfully synthesized with three different methods namely i) modified direct-mixing method ii) microwave assisted method and iii) autoclave assisted method without using surfactants. Palm oil derived fatty alcohol (PODFA), dodecyl alcohol (C8) was used as renewable non-surfactant template. Four prominent peaks were observed in all three samples attributable to the reflection planes of (200), (220), (400) and (420) of a cubic structure at ca. 2θ = 6.9°, 9.6°, 13.7° and 15.2°. The morphology of MOF-5 produced using modified direct-mixing method was faceted structure with average size of ca. 1 μm. In addition, the morphology of MOF-5 produced using microwave assisted synthesis was cubic structure with average size of ca. 8.34 μm. However, the morphology of MOF-5 using autoclave assisted method was interpenetrated cubic with average size of ca. 22.65 μm.

UR - http://www.scopus.com/inward/record.url?scp=84966586699&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=84966586699&partnerID=8YFLogxK

U2 - 10.1088/1755-1315/32/1/012060

DO - 10.1088/1755-1315/32/1/012060

M3 - Conference article

AN - SCOPUS:84966586699

VL - 32

JO - IOP Conference Series: Earth and Environmental Science

JF - IOP Conference Series: Earth and Environmental Science

SN - 1755-1307

IS - 1

M1 - 012060

ER -