Behavior of layered double hydroxides having different divalent transition metal groups

M. Mamat, T. Tagg, Wan M. Khairul, M. A.A. Abdullah, N. Mohd Tahir, Zaemah Jubri @ Mohd Zufri, R. A. As'ari

Research output: Chapter in Book/Report/Conference proceedingConference contribution

3 Citations (Scopus)

Abstract

The layered double hydroxides (LDHs) with different divalent transition metal groups and nitrate as a counter anion were investigated. Three d-block divalent metals namely cobalt (Co), nickel (Ni) and copper (Cu) were selected. The cobalt/aluminium (CoAN)-, nickel/aluminium (NiAN)- and copper/aluminium (CuAN)-layered double hydroxides were successfully synthesized via coprecipitation method. All the obtained LDHs were characterized by PXRD, FT-IR, ICP-OES, CHNS and TGA/DTG analysis. Interestingly, behavior of the LDHs was dependent on the size of divalent cations. PXRD showed the basal spacing decrease in the order NiAN (0.88nm)> CuAN (0.87nm) > CoAN (0.74nm), and in a linear correlation with the increasing radii of the divalent cations. Similar trend is observed for the weight loss of LDHs, where NiAN has the highest weight loss (53%), followed by CuAN (43%) and CoAN (34%). Further elemental analysis showed the content of trivalent metal cations, nitrate anions and water molecules in the LDHs decrease with the increasing radii.

Original languageEnglish
Title of host publicationSensors and Materials
Subtitle of host publicationAdvanced Researches
PublisherTrans Tech Publications
Pages94-101
Number of pages8
ISBN (Print)9783038351191
DOIs
Publication statusPublished - 01 Jan 2014
Event2014 International Conference on Sensors and Materials Manufacturing Science, ICSMMS 2014 - Hangzhou, China
Duration: 11 Apr 201412 Apr 2014

Publication series

NameApplied Mechanics and Materials
Volume563
ISSN (Print)1660-9336
ISSN (Electronic)1662-7482

Other

Other2014 International Conference on Sensors and Materials Manufacturing Science, ICSMMS 2014
CountryChina
CityHangzhou
Period11/04/1412/04/14

Fingerprint

Transition metals
Aluminum
Cobalt
Nickel
Positive ions
Nitrates
Negative ions
Copper
Coprecipitation
Metals
Molecules
Chemical analysis
Water

All Science Journal Classification (ASJC) codes

  • Engineering(all)

Cite this

Mamat, M., Tagg, T., Khairul, W. M., Abdullah, M. A. A., Mohd Tahir, N., Jubri @ Mohd Zufri, Z., & As'ari, R. A. (2014). Behavior of layered double hydroxides having different divalent transition metal groups. In Sensors and Materials: Advanced Researches (pp. 94-101). (Applied Mechanics and Materials; Vol. 563). Trans Tech Publications. https://doi.org/10.4028/www.scientific.net/AMM.563.94
Mamat, M. ; Tagg, T. ; Khairul, Wan M. ; Abdullah, M. A.A. ; Mohd Tahir, N. ; Jubri @ Mohd Zufri, Zaemah ; As'ari, R. A. / Behavior of layered double hydroxides having different divalent transition metal groups. Sensors and Materials: Advanced Researches. Trans Tech Publications, 2014. pp. 94-101 (Applied Mechanics and Materials).
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abstract = "The layered double hydroxides (LDHs) with different divalent transition metal groups and nitrate as a counter anion were investigated. Three d-block divalent metals namely cobalt (Co), nickel (Ni) and copper (Cu) were selected. The cobalt/aluminium (CoAN)-, nickel/aluminium (NiAN)- and copper/aluminium (CuAN)-layered double hydroxides were successfully synthesized via coprecipitation method. All the obtained LDHs were characterized by PXRD, FT-IR, ICP-OES, CHNS and TGA/DTG analysis. Interestingly, behavior of the LDHs was dependent on the size of divalent cations. PXRD showed the basal spacing decrease in the order NiAN (0.88nm)> CuAN (0.87nm) > CoAN (0.74nm), and in a linear correlation with the increasing radii of the divalent cations. Similar trend is observed for the weight loss of LDHs, where NiAN has the highest weight loss (53{\%}), followed by CuAN (43{\%}) and CoAN (34{\%}). Further elemental analysis showed the content of trivalent metal cations, nitrate anions and water molecules in the LDHs decrease with the increasing radii.",
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Mamat, M, Tagg, T, Khairul, WM, Abdullah, MAA, Mohd Tahir, N, Jubri @ Mohd Zufri, Z & As'ari, RA 2014, Behavior of layered double hydroxides having different divalent transition metal groups. in Sensors and Materials: Advanced Researches. Applied Mechanics and Materials, vol. 563, Trans Tech Publications, pp. 94-101, 2014 International Conference on Sensors and Materials Manufacturing Science, ICSMMS 2014, Hangzhou, China, 11/04/14. https://doi.org/10.4028/www.scientific.net/AMM.563.94

Behavior of layered double hydroxides having different divalent transition metal groups. / Mamat, M.; Tagg, T.; Khairul, Wan M.; Abdullah, M. A.A.; Mohd Tahir, N.; Jubri @ Mohd Zufri, Zaemah; As'ari, R. A.

Sensors and Materials: Advanced Researches. Trans Tech Publications, 2014. p. 94-101 (Applied Mechanics and Materials; Vol. 563).

Research output: Chapter in Book/Report/Conference proceedingConference contribution

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N2 - The layered double hydroxides (LDHs) with different divalent transition metal groups and nitrate as a counter anion were investigated. Three d-block divalent metals namely cobalt (Co), nickel (Ni) and copper (Cu) were selected. The cobalt/aluminium (CoAN)-, nickel/aluminium (NiAN)- and copper/aluminium (CuAN)-layered double hydroxides were successfully synthesized via coprecipitation method. All the obtained LDHs were characterized by PXRD, FT-IR, ICP-OES, CHNS and TGA/DTG analysis. Interestingly, behavior of the LDHs was dependent on the size of divalent cations. PXRD showed the basal spacing decrease in the order NiAN (0.88nm)> CuAN (0.87nm) > CoAN (0.74nm), and in a linear correlation with the increasing radii of the divalent cations. Similar trend is observed for the weight loss of LDHs, where NiAN has the highest weight loss (53%), followed by CuAN (43%) and CoAN (34%). Further elemental analysis showed the content of trivalent metal cations, nitrate anions and water molecules in the LDHs decrease with the increasing radii.

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Mamat M, Tagg T, Khairul WM, Abdullah MAA, Mohd Tahir N, Jubri @ Mohd Zufri Z et al. Behavior of layered double hydroxides having different divalent transition metal groups. In Sensors and Materials: Advanced Researches. Trans Tech Publications. 2014. p. 94-101. (Applied Mechanics and Materials). https://doi.org/10.4028/www.scientific.net/AMM.563.94